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Size Matters--in Quantum Mechanics

  We saw that bullets do not give rise to an interference pattern but electrons do. The question is why. We can answer this by looking at the difference between a bullet and an electron. A bullet is much more massive than an electron. Its velocity (typically) is also much lower than that of an electron's. So let's first make the velocities equal. Do we now get interference with the bullet? We need to determine the wavelength of a bullet. The wavelength is about 10^-12 smaller than that of an electron even if both are moving at the same speed. This arises because of the mass difference between a bullet and an electron. As the wavelength of a particle gets smaller and smaller, can we resolve its wave-like characteristics? The answer is no. Wavelike nature goes away as the wavelength gets smaller and smaller. Objects with vanishingly small wavelengths appear continuous. Hence, there is no interference. This is the key. Quantum mechanics becomes important when objects have wavelengths that are on the atomic scale. Should the wavelength be less than atomic length scales, then we need not worry about quantum mechanics. Such objects appear continuous and we can think about them in our usual classical way. Another way of thinking about this is to consider what happens when the spacing between the slits goes off to infinity. There is no overlap of the waves and hence no interference. This tells us that if we were to devise an experiment to see the interference of bullets, we would have to have the slits so close together that it would be impossible to determine which slit the bullets went through. The separation between the slits would have to be on the order of half the wavelength of a bullet. Such length scales are not possible. This further shows you that bullets and electrons only differ quantitatively. In quantum mechanics, size matters.

 

 

The Copenhagen Interpretation (Sklar, pp. 172-175)

We will start with the most widely espoused interpretation of what QM "means." Different interpretations do not necessarily give different predictions, so they are not different theories. (But there are also "interpretations" which require that the theory ultimately be changed, and then subtle experimental predictions do change.) The CI was developed by Bohr, Heisenberg, etc, and never accepted by Einstein, Schrodinger, DeBroglie…

The CI adopts two principles:

The dichotomy between the QM and classical realm is fundamental to the Copenhagen Interpretation. Some other QM interpretations and modifications try to avoid it, and some try to make it a result of a unified theory, not a dualistic assumption.

 

 

There are several issues to be studied:

 

 

Determinism, objectivity, and probability: Classical physics vs. QM

We need to make these concepts clear, because they become issues in QM.

 

Determinism in classical physics:

Remember that, in principle, with adequate information predictions can be made with certainty. Some difficulties:

• Integrable systems are well behaved, but chaotic systems are not. Our predictive power is severely constrained.

• Systems are never completely isolated, so there will always be unforeseen disturbances.

• Newtonian determinism does not prescribe a causal interpretation.

 

 

 

Objectivity: When does a phenomenon objectively exist?

Weak form: Independent observers can verify it (intersubjectivity). Berkeley claimed that was the only objectivity there is.

There are three points:

 

Determinism, objectivity, and probability in QM

What is the standard quantum description?

Formally, QM describes an ensemble of identically prepared systems. "Identical" means that they are all described by the same wave function. Then, we can use our machinery of probability to describe what will happen.

But in practice, we all assume that QM really provides some statement about ANY system, since Heraclitus is still right that the world does not contain ensembles of absolutely identically prepared systems.

The state vector |Y> (a fancy term for wave function which avoids the connotation of any specific space or time dependence) contains the complete description of the ensemble. Probabilities are calculated from the square of the wave function.

In the absence of a "measurement", the state vector evolves in a smooth, deterministic way with time, as described by Schrödinger’s equation.

 

 

Measurements are made on individual systems taken from the ensemble. The results of measurements are always one of the eigenvalues (this is a fancy word for mutually compatible outcomes) of the measured property of the system. In fact, that's just a definition:

A measurement of some property of a micro-system is an interaction with a macro-system, such that the observed outcomes correspond to eigenvalues of the operator representing that property of the microsystem.

For momentum, there is a continuous range of possibilities, but for spin, the set of results is discrete. The state vector tells us the probability of obtaining each eigenvalue.

If we make a measurement of quantity A, and obtain result Ai, then the wave function immediately after the measurement is in an eigenstate corresponding to Ai. That is, the probability of obtaining Ai again (if done immediately) is 100%. This is sometimes called the projection postulate, or collapse of the wave function.

A reminder: an atom does NOT have to be in some state with a special energy value (an eigenvalue). If the energy is measured, the outcome DOES have to be one of those special values.

 

Determinism

Despite QM's probabilistic nature, there remains a lot of determinism:

However, unlike classical physics, standard QM says that the probabilities are not the result of a pseudo-indeterminism arising from the lack of knowledge of the system. There is no more knowledge to be had, no hidden information.

 

Probability

The frequentist interpretation makes no sense when we are talking about a single atom. The subjectivist interpretation now has to include some irreducible ignorance, which does not contradict the general idea that there is also reducible ignorance, prior knowledge, etc.

 

Objectivity

Which things exist when we aren’t looking? Perhaps quantities such as mass and electrical charge, because they don’t change when we look. Maybe the probability distribution itself. We’ll investigate this later.

Two important questions:

1 Is the state vector an objective property of the object?

2 If the state vector was not an eigenstate of A before the measurement, it becomes one afterwards. Thus, after the measurement, A seems to have an objective existence. Did it exist before the measurement?

Either answer to 1 gives us problems. If yes, how can it change discontinuously when a measurement is made? This is not only a time discontinuity, but also spatial. If we can avoid the collapse of the wave function, then we might avoid this problem. If no, then how does it give rise to physical effects such as interference? We’ll deal with question 2 later.

 

The central problem, which we will keep coming back to, is that the idea of "measurement" as a break in the behavior keeps coming up- but we haven't said why some interactions between things constitute measurements and others don't.

 

Just a preview: there will be some problems left.

If the only problems with QM were that it was not fully deterministic, or that it said that our old ideas about waves and particles didn't describe the world, or that quantities like "momentum" do not generally have precise values, my response would be "Live with it." Relativity has already taught us not to put too much stake in our prior prejudices. We'll see, however, that QM asks us to give up much more, so that it is not quite clear what it is saying about the world, even though we know exactly how to use it to make predictions about almost all experiments. We'll also see that just plain experiment forces us to give up nearly as much of our basic worldview as QM theory does.

 

A quantum description of "measurement".

The macroscopic set-up creates a situation describable by y (which describes the quantum system) and j (which describes the macroscopic apparatus).

Initially, these are independent, so if y has two possible values, y1 and y2, the overall wavefunction of the whole thing would be

y changes in time, as described by the Schrödinger equation.

When the micro-system (say a single particle) encounters a measurement apparatus, the wave functions describing the particle and the apparatus become "entangled", i.e. they are no longer independent. Either y goes into state 1, and all the needles, etc represented by j go to read "1", or each goes to "2."

So far, we have just described how the wave-function obeys the equation.

Interference between possibilities (1) and (2) now disappears, because there are zillions of particles in different positions in , and there is no chance whatever that the waves representing these two possibilities will overlap.

 

Here's the key point: if you have just one particle, going through two slits, the two paths show interference only if they get to the same place. The (x,y,z,t) coordinates must all be the same. The wave function representing MANY particles is a function of ALL their coordinates, so if there are two lumps of this wave function evolving in time, they show interference only if ALL the coordinates of ALL the particles can get to the same places by each path, at the same time. This simply never happens once many particles are involved in a complicated system.

Thus we now have two distinct possibilities, represented by

.

 

We now have gotten rid of the interference, while postulating nothing different from the linear wave equation, and without worrying about "duality" or any such philosophy.

The "projection postulate" turns out to follow naturally: obeying the wave eq, represents a situation in which, if the apparatus measures y again, it will get the same result. That is, no piece of the wavefunction represents a solution with the successive spin readings along the same axis giving opposite results.

So why is there any philosophical problem about QM, other than the usual shedding old ideas?

 

At this point the solution to the equation gives us: Both distinct possibilities are still there, even though they don't interfere!

Why should you be troubled that both possibilities remain?

Schrödinger's cat:

Say that the micro-variable is a quantum spin, and the measurement apparatus is set up to kill a cat if the spin is up, and give it some food and water if the spin is down. This is not a science-fiction idea, but a relatively trivial thing to set up in an ordinary lab.

The result of the solution of the linear wave equation is that the cat is both alive and dead, in a superposition. This does not mean "in a coma" or "almost dead" but BOTH fully alive and purring or thoroughly dead and decomposing.

 

Furthermore, once you look, your wave function becomes entangled with those of the cat, etc. The solution of the linear wave equation now describes a superposition of a you who has seen the dead cat and a you who has seen the live cat!

Which of youse guys is for real?

The linear wave equation by itself does not describe the world of our experience!

 

What does describe our experience?

The most extreme version of the orthodox Copenhagen view is that the wave function was never real, just an algorithm for predicting experiences, which are the only reality.

The common folk view among physicists is that the wave function somehow "collapses" to one of the possibilities, following the Born probability rules.

Some physicists hold to a sort of hybrid of these rules.

 

The orthodox resolution (see Rohrlich, pp 166-169)

Many physicists will give this resolution, or something similar.

There are two steps to the argument.

Remember the two slit experiment. The reason we get in trouble when we try to say that the electron really went through one slit or the other is that would destroy the interference between the two paths. However, when we are in a situation where there is no interference pattern to begin with, then what prevents us from making that kind of either/or statement?

The first step of the argument is not very controversial. A macroscopic apparatus is very complex and much larger than any relevant wavelengths, so interference vanishes to truly immeasurable levels. This phenomenon is called decoherence. It appears in the classical physics of waves, and is not a quantum mystery.

The second step is more problematic. We must face the question, "Exactly when is a particular result realized?" The problem with the orthodox resolution is that it forces us to attach different words (meanings) to the same mathematical quantities in different situations.

 

A problem with the orthodox resolution

In the microscopic realm, a superposition y1+y2 does not imply that the system is definitely in one state or the other. In fact, interference effects preclude drawing that conclusion.

When we make a measurement, the superposition is directly transposed onto the apparatus: Y1+Y2. Why do we now give a different meaning to the wave function? It is true that the interference argument no longer applies, but there are no other cases where the meaning we attach to the mathematical formalism varies with the context. That variability eviscerates the usefulness of the interpretation.

One can push the argument farther. As the information passes through the measuring device from the microscopic to the macroscopic realm, the possibility of observing interference gradually disappears. At what point are we allowed to reassign meaning?

Isn't the verbal trick by which the meaning of y is reassigned at some point just a way of avoiding saying "at some point the wave function quits obeying the wave equation and collapses"?

Next time, we’ll discuss why people hesitate to say "the wave function collapses" and some alternative ways of dealing with this issue.